Product ID:FYRQUEL 220 MLT
MSDS Date:03/08/1999
FSC:9150
NIIN:01-113-2046
MSDS Number: CGMJD

Emergency Phone: 914-693-6946

Info Phone: 800-666-1200

Preparer: NOT PROVIDED

Cage: 97854

Telephone: 504-366-9105

Cage: 0PGK2

BUTYLATED TRIPHENYL PHOSPHATE MIXTURE

TRIPHENYL PHOSPHATE

CAS: 115-86-6

RTECS: TC8400000

OSHA PEL 3 MG/M3

ACGIH TLV: 3 MG/M3; 9596

LD50 LC50 Mixture:LD 50 ORAL RAT IS > 5000 MG/KG.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYES: CONTACT MAY CAUSE MILD
IRRITATION. SKIN: MAY CAUSE MILD IRRITATION. INHALATION: MAY CAUSE
RESPIRATORY TRACT IRRITATION. PRODUCT CONTAINS TRIPHENYL PHOSPHATE
WHICH CAN CAUSE CHOLINESTERASE INHIBI TION. INGESTION: MAY CAUSE
IRRITATION OFGASTROINTESTINAL SYSTEM AND DIARRHEA, AND
CHOLINESTERASE INHIBITION. TARGET ORGANS: SKIN, EYES, RESPIRATORY
SYSTEM, CENTRAL & PERIPHERAL NERVOUS SYSTEM.
Explanation of Carcinogenicity:NONE OF THE INGREDIENTS IN THIS PRODUCT
IS LISTED BY NTP, IARC OR OSHA AS A CARCINOGEN.
Effects of Overexposure:EYES: IRRITATION. SKIN: IRRITATION. INHALATION:
IRRITATION, HEADACHE, NAUSEA, SWEATING, HANDS AND FEET NUMBNESS,
SALIVATION, MUSCLE TWITCHING, TREMORS, INCOORDINATION, BLURRED
VISION, TEARS, ABDOMINAL CRAMPS, DIARRHEA, CHEST DISCOMFORT.
INGESTION: IRRITATION OF GI TRACT, AND THE SYMPTOMS LISTED UNDER
INHALATION. IN CASES OF CHOLINESTERASE INHIBITION, ATROPINE BY
INJECTION IS ANTIDOTAL. PRALIDOXIME CHLORIDE (2-PAM; PROTOPAM
CHLORIDE) IS ALSO ANTIDOTAL WHEN ADMINISTERED EARLY & IN
CONJUNCTION WITH ATROPINE.
Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING
NEUROMUSCULAR DISORDERS MAY BE AT AN INCREASED RISK FROM EXPOSURE
TO THIS MATERIAL.

First Aid:EYES: REMOVE CONTACT LENSES. FLUSH EYES WITH LARGE AMOUNTS OF
WATER HOLDING EYELIDS OPEN. GET MEDICAL ATTENTION. SKIN: REMOVE
CONTAMINATED CLOTHING. WASH AREA WITH SOAP AND WATER. IF IRRITATION
DEVELO PS GET MEDICAL ATTENTION. INHALATION: MOVE TO FRESH AIR. IF
NOT BREATHING GIVE CPR. IF BREATHING DIFFICULT GIVE OXYGEN. GET
MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING UNLESS
DIRECTED TO DO S O BY MEDICAL PERSONNEL. IIF VOMITING OCCURS, KEEP
HEAD BELOW HIPS TO REDUCE RISK OF ASPIRATION. NEVER GIVE ANYTHING
BY MOUTH IF UNCONSCIOUS. GET MEDICAL ATTENTION.

Flash Point Method:PMCC
Flash Point:=246.1C, 475.F
Autoignition Temp:Autoignition Temp Text:N/D
Extinguishing Media:USE WATER FOG 0R SPRAY, DRY CHEMICAL, FOAM, CARBON
DIOXIDE.
Fire Fighting Procedures:FIRE FIGHTERS SHOULD USE NIOSH APPROVED
FULL-FACE, SCBA AND IMPERVIOUS PROTECTIVE CLOTHING. USE WATER SPRAY
TO COOL FIRE-EXPOSED CONTAINERS TO PREVENT RUPTURE. DIKE FIRE
CONTROL WATER FOR LATER DISPOS AL.
Unusual Fire/Explosion Hazard:HIGH PRESSURE WATER MAY SPREAD PRODUCT
FROM BROKEN CONTAINERS INCREASING CONTAMINATION OR FIRE HAZARD. DO
NOT ALLOW CONTAMINATED WATER TO ENTER WATERWAYS. PRODUCT IS NOT
FLAMMABLE OR COMBUSTIBLE.

Spill Release Procedures:VENTILATE AREA. STOP SOURCE OF SPILL AND DIKE
AREA. ABSORB LIQUID WITH INERT MATERIAL AND PLACE IN COVERED
DISPOSAL CONTAINER. BRUSH AREA WITH DETERGENT AND WATER. DIKE WATER
FOR DISPOSAL. DO NOT ALLO W CONTAMINATED WATER TO ENTER WATERWAYS
OR SEWERS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:MAX STORAGE TEMP: 149F. STORE IN COOL,
DRY, WELL VENTILATED AREA AWAY FROM FOODSTUFFS, FLAMMABLE OR
OXIDIZING MATERIALS AND SOURCES OF HEAT OR FLAME.
Other Precautions:PROTECT CONTAINERS FROM DAMAGE. AVOID PROLONGED
STORAGE AT ELEVATED TEMPERATURES UNDER WET ALKALINE OR ACIDIC
CONDITIONS. ROTATE CONTAINERS REGULARLY (FIRST IN, FIRST OUT).
PREVENT MOISTURE CONDENSATI ON IN THE CONTAINERS.

Respiratory Protection:NONE REQUIRED WITH ADEQUATE VENTILATION. WHERE
ADEQUATE VENTILATION IS NOT AVAILABLE USE NIOSH-APPROVED RESPIRATOR
WITH DUST, MIST AND FUME FILTERS. FOR HIGHER LEVEL OF PROTECTION
USE NIOSH- APPROVED POSITIVE-PRESSURE, AIR-SUPPLIED RESPIRATOR.
Ventilation:PROVIDE ADEQUATE VENTILATION TO MAINTAIN EXPOSURE BELOW THE
RECOMMENDED TLV/PEL.
Protective Gloves:COMBINATION NEOPRENE OVER NATURAL LATEX ARE
RECOMMENDED
Eye Protection:CHEMICAL SAFETY GOGGLES OR FACESHIELD.
Other Protective Equipment:PROTECTIVE CLOTHING AS REQUIRED TO MINIMIZE
EXPOSURE. EYE WASH STATION AND SAFETY SHOWER. LONG SLEEVED
CLOTHING.
Work Hygienic Practices:WASH AFTER HANDLING AND BEFORE EATING,
DRINKING, OR SMOKING. LAUNDER CONTAMINATED CLOTHING BEFORE REUSE.
Supplemental Safety and Health
ALL FOOD SHOULD BE KEPT IN A SEPARATE AREA AWAY FROM THE STORAGE/USE
LOCATION. EATING, DRINKING, AND SMOKING SHOULD BE PROHIBITED IN
AREAS WHERE THERE IS A POTENTIAL FOR SIGNIFICANT EXPOSURE TO THIS M
ATERIAL.

HCC:V7
Vapor Pres:<0.1 @100F
Solubility in Water:<0.1 GM/100 ML
Appearance and Odor:CLEAR, TRANSPARENT LIQUID, ESSENTIALLY ODORLESS.

Stability Indicator/Materials to Avoid:YES
STRONG OXIDIZERS, STRONG ACIDS, STRONG ALKALIS. HYDROLYZES SLOWLY AT
AMBIENT TEMPERATURE IN ACIDIC OR ALKALINE AQUEOUS SOLUTIONS.
Stability Condition to Avoid:STABLE AT AMBIENT TEMPERATURES AND
ATMOSPHERIC PRESSURE. IT IS NOT SELF REACTIVE AND NOT SENSITIVE TO
STATIC DISCHARGE.
Hazardous Decomposition Products:VAPORS MAY DECOMPOSE AT ELEVATED
TEMPERATURES TO RELEASE HARMFUL MATERIALS. UNDER WET ACIDIC OR
ALKALINE CONDITIONS HYDROLYZES TO FORM PHENOL, SUBSTITUTED PHENOLS,
AND ARYL PHOSPHORIC ACIDS.

Waste Disposal Methods:CONTACT YOUR LOCAL ENVIRONMENTAL OFFICER.
DISPOSE OF IN ACCORDANCE WITH ALL FEDERAL, STATE AND LOCAL
REGULATIONS.

Toxicological Information:LC50 INH-RAT: >3.1 MG/L, 4 HR. NO EFFECTS
OBSERVED AT THIS LEVEL. CHRONIC EFFECTS NOT KNOWN. LD50 SKN-RBT
>2000 MG/KG, MILD SKIN IRRITANT IN RABBITS FOLLOWING 24 HR
EXPOSURE. CHRONIC DERMAL NOT KNOWN. EXPECTED TO CAUSE IRRITATION.
MILD IRRITANT TO RABBIT EYES. DAILY INGESTION BY RATS OF 100, 400
OR 1600 PPM FOR 3 MONTHS PRODUCED INCREASES IN LIVER WEIGHTS OF
MALES AT HIGH-DOSE LEVEL. NO HISTOPATHO LOGICAL CHANGES NOTED.
CARCINOGENITY/MUTAGENICITY: NO EFFECTS NOTED. REPRODUCTIVE: RATS:
DAYS 6-20 OF GESTATION: INCREASED LIVER WEIGHTS & FETO-TOXICIITY.
NO TERATOGENICITY NOTED. NO NEUROTOXICITY NOT ED.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:96-HR LC50 RAINBOW TROUT: > 2 MG/L, 96-HR LC50 SHEEPSHEAD
MINNOW: > 1 MG/L, 96-HR LC50 MYSID SHRIMP: 0.39 MG/L. TRIARYL
PHOSPHATE ESTERS, INCLUDING TRIPHENYL PHOSPHATE EXHIBIT LOW AQUEOUS
SOLUABILITY, HAVE MODERATE POTENTIAL FOR BIOACCUMULATION, AND
READILY UNDERGO BIODEGRADATION. CHEMICAL FATE: MATERIAL IS READILY
BIODEGRADABLE. HYDROLYSIS RATES FOR TRIPHENYL PHOSPHATE, A PRODUCT
COMPONENT, ARE: AT PH 9.5: HALF-LIFE: 0.23 DAYS, AT PH 8.2:
HALF-LIFE: 7.5 DAYS.

Transport Information:ENVIRONEMTALLY HAZARDOUS SUBSTANCE, LIQUID,
N.O.S. (TRIPHENYL PHOSPHATE), 9, UN3082, PG III. NORTH AMERICAM
EMERGENCY RESPONSE GUIDE NO: 171, LABEL: CLASS 9, SUBSIDIARY RISK:
MARINE POLLUTANT.

SARA Title III Information:NOT RELEVANT
Federal Regulatory Information:TRIPHENYL PHOSPHATE SUBJECT TO DOMESTIC
SUBSTANCE LIST - CANADA. LISTED ON TSCA
State Regulatory Information:TRIPHENYL PHOSPHATE LISTED ON
MASSACHUSETTS SUBSTANCE LIST, NEW JERSEY R-T-K HAZARDOUS SUBSTANCE,
PENNSYLVANIA HAZARDOUS SUBSTANCE LIST.